In H 2, we have 2 hydrogen atoms, each with a 1s orbital. Hydrogen bond hclo intermolecular forces have dipole-dipole force. hydrogen INTERMOLECULAR BONDING - HYDROGEN BONDS This is because the oxygen atom, in addition to forming bonds with the hydrogen atoms, also carries two pairs of unshared electrons. yes . The movement of the replication fork is accomplished by the enzyme helicase, which breaks hydrogen bonds between the paired bases and unwinds the double helix ahead of the advancing DNA polymerase. E) All of the above. Hydrogen bonding is the strongest form of intermolecular attractions. Email Address . If 1.0 mol each of H2, I2, and HI were placed together in a 1-L container at 425°C, then. A molecule that has hydrogen bonding usually follows these two premises.. Hydrogen bonds have about a tenth of the strength of an average covalent bond, and are constantly broken and reformed in liquid water. It results from the attractive force between a hydrogen atom covalently bonded to a very electronegative atom such as a N, O, or F atom and another very electronegative atom. Covalent molecules made of only one type of atom, like hydrogen gas (H2), are nonpolar because the hydrogen atoms share their electrons equally. 1.) Ans: No. Definition Hydrogen bonding is a weak type of force which forms a dipole-dipole interaction between two molecules within the same molecule. yes phenol does show hydrogen bonding.the delocalized electron ring attracts the lone pair electrons of oxygen of hydroxyl group as along with … [J. Phys. Bonding What Causes Hydrogen Bonding? - ThoughtCo This is shown in the graphic on the left for a similar set … A chlorine atom has 7 electrons in its outer shell. In water, each hydrogen nucleus is covalently bound to the central oxygen atom by a pair of electrons that are shared between them. Hydrogen bonding is strong electrostatic forces of attraction between positively charged h+ cation directly bonded to negatively charged lone pair... H 2 is a gas which forms when two hydrogen atoms bond together and become a hydrogen molecule. Enter your email address to subscribe to this blog and receive notifications of new posts by email. Whenever hydrogen is bonded to N, O or F, the dipoles are so large that they have their own special name....hydrogen bonding. 20 seconds . In fact, Fluorine is more electronegative than Oxygen, so technically, H F should engage in more hydrogen bonding than water. Therefore the element with the greatest total number of electrons will have the highest boiling point (iodine) and the element with the smallest total number of electrons will have the lowest boiling point (hydrogen). Hydrogen bonds can form between different molecules (intermolecular hydrogen bonding) or between different parts of the same molecule (intramolecular hydrogen bonding). Does NH 3 have hydrogen bonding? The hydrogen bond is one of the strongest intermolecular attractions, but weaker than a covalent or an ionic bond. and its types. it is windly attack between positive end to negative end. What type of intermolecular force is H2 H2? Hydrogen bonding occurs between a hydrogen atom linked to an electronegative atom and an electronegative atom belonging to same or another nearby m... What kind of intermolecular forces are present in H2?, The most significant intermolecular force for this substance would be dispersion forces. a) (CH3)3N b) CH3-O-CH3 c) CH3CH2-OH d) CH3CH2-F e) HI ** (e) cant be the answer becuz it doesnt have any Hydrogen Bonds (N,O,F) ** (a) cant be the answer becuz the N atom is by itself. This results in ΔH vap being larger than ΔH fus. Hydrogen bonding occurs in highly negative atoms like F,O,N etc Despite S is of O family,it has reduced electronegativity as compared to F,O,N …. S... 30 seconds . For hydrogen bonding there must be enough diffrence between electronegativity of hydrogen and the other element. But in case of hydrogen sulphide t... What is the strongest type of intermolecular force present in CHF3. Subscribe . This is an indication that hydrogen bonds have a partial covalent character. HF and NH3 can both form 2 Hydrogen bonds. Account for this. Chlorine is in group 7 of the periodic table. HF has a higher boiling point than HBr because of hydrogen bonds. Additional information: Chlorine has a high electronegativity, but it does not show H-bonding since it has a greater size. B) Water is the main solvent within living organisms. answer choices . Second the O, N, or F must be connected to a less Electronegative atom or again hydrogen bonding is not possible because it would not gain a partial negative charge. In water, each hydrogen nucleus is covalently bound to the central oxygen atom by a pair of electrons that are shared between them. no . H2O < HF < HBr because of IMF strength – stronger IMF means lower VP. Hydrogen can only form 1 bond. In H 2 O, only two of the six outer-shell electrons of oxygen are used for this purpose, leaving four electrons which are organized into two non-bonding pairs. Q. alternatives . The hydrogen bond is responsible for many of the anomalous physical and chemical properties of compounds of N, O, and F. In particular, intermolecular hydrogen bonding is responsible for the high boiling point of water (100 °C) compared to the other group-16 hydrides that have much weaker hydrogen bonds. There are many important consequences of the effects of hydrogen bonding between water molecules:Hydrogen bonding makes ice less dense than liquid water, so ice floats on water.The effect of hydrogen bonding on heat of vaporization helps make perspiration an effective means of lowering temperature for animals.The effect on heat capacity means water protects against extreme temperature shifts near large bodies of water or humid environments. ... The partially positive end of hydrogen is attracted to the partially negative end of the oxygen, nitrogen, or fluorine of another molecule. H F, N 2 H 4 and C H 3 O H have significant intermolecular hydrogen bonding. Report an issue . /2 Methanol and ethanol have hydrogen bonds. yes. Like all mathematical functions, it can have positive values and negative values. yes. 1. A hydrogen bond is a dipole-dipole force and is an attraction between a slightly positive hydrogen on one molecule and a slightly negative atom on another molecule. H 2 is a gas which forms when two hydrogen atoms bond together and become a hydrogen molecule. An example occurs in the molecule H3NBH3 where the hydrogen atoms on nitrogen have a partial positive charge and the hydrogen atoms on boron have a partial negative charge. Answer: Hydrogen atoms in compounds such as H2 and H2O are joined to the molecule with covalent bonds. This is where electrons are shared between the atoms in order to fill there valence shells. Hydrogen must be bonded to a highly electronegative element which are nitrogen ($\ce{N}$), fluorine ($\ce{F}$) and oxygen ($\ce{O}$).Seeing that both oxygen and chlorine have a small difference in their electronegativity (oxygen being roughly 3.5 … no. Join 3 other subscribers. 2. In a very recent development, hydrogen bonds have been noted between two hydrogen atoms having opposite polarity. Hydrogen bonding is another intermolecular force, which is stronger than London and dipole-dipole forces. Only CH₃NH₂ and CH₃OH can have hydrogen bonds between other molecules of the same kind.. To have hydrogen bonding, you need an N, O, or F atom in one molecule and an H attached to an N, O, or F atom in another molecule.. See What is a Hydrogen bond?. SO2 can’t form hydrogen bonds because there is no hydrogen. 4. Source. Water, having hydrogen bound to an oxygen (which is much more electronegative than hydrogen, thus not … Hydrogen bonds vary in strength. The single strands of DNA so created are prevented from rejoining by single-strand binding proteins. AND Will it have the highest or the lowest boiling point ? The four electron pairs surrounding the oxygen tend to arrange themselves as far from … CH₃F has an F atom, but no H-F bonds It cannot form hydrogen bonds with other CH₃F molecules. 1. H2 is also called molecular hydrogen. H2 2. HF forms only one hydrogen bond per molecule as it only has one hydrogen atom. - Neither hydrogen nor iodine changes oxidation states, so the … Answer (1 of 10): I will give two answers ; one short and another a bit long Short answer: Hydrogen bond is formed between two molecules if they have hydrogen and any of the three electronegative atoms (N,O,F) covalently bonded to each other . CH4 3. 1,4-Dichlorobenzene D 2h. Hello, reders welcome to another fresh article on “textilesgreen.in” today we will discuss about hclo intermolecular forces. Here students have to examine the formation of different types of bonds like a covalent bond or hydrogen bond understand different rules and theories as well as hybridisation. H2S Hybridization. answer choices . There is a hydrogen atom involved. H2(g) + 12(g) + 2H1(g) A student makes the following statements: - Hydrogen always has the same oxidation number, so it has an oxidation number of +1 in both the reactant H2 and product Hi. whereas, h2o exhibits hydrogen bonding. In the potential energy simulation, why does the potential energy between the atoms decrease as you move them closer together? It has a melting point of -118.50 F and a boiling point of about 670 F. HF has a molar mass of 20.0064 g/mol and a density of 1.15 g/litre as a gas at 250 C. In hydrogen iodide _____ are the most important intermolecular forces. Is h2 a polar covalent bond? D) Water has strong hydrogen bonding. $\endgroup$ – A hydrogen atom has 1 electron in its outer shell. H atom is attached to C atom and therefore cant bond with the N atom. Hydrogen bonds have about a tenth of the strength of an average covalent bond, and are constantly broken and reformed in liquid water. That is why CH3F does not have hydrogen bonding. Tags: Question 12 . #2. SURVEY . In water for example; hydrogen atoms in a molecule of water have a partial positive charge while the oxygen atom has a … First we have to understand the fact that the hydrogen bond is basically very strong dipole interactions. This is favored by high electronegative a... asked Sep … What type of elements form covalent bonds? (a) H2S molecule: Two hydrogen atoms, and two lone non-bonding electron pairs. This attraction created by hydrogen bonding keeps water in a liquid phase over a wide range of temperatures. 30 seconds . Symmetrical molecules are nonpolar. View this answer. B) NH3. Choose the pair of substances that are most likely to form a homogeneous solution. The water tries to maximize its interaction with the surface and, as a result, “crawls” up the size of the glass tubing forming the meniscus. SURVEY . ... Identify the compound that does not have hydrogen bonding. In HCN, the hydrogen is connected to the carbon not O, N ,or F. Therefore the answer much be H3BO3. Water molecules form hydrogen bonds between each other and have strong intermolecular force; as a result, a strong surface tension is created. Consequently it is the most common form of Hydrogen because it is stable with a neutral charge. Any molecule which has a hydrogen atom attached directly to an oxygen or a nitrogen is capable of hydrogen bonding.Hydrogen bonds also occur when hydrogen is bonded to fluorine, but the HF group does not appear in other molecules.. Is CCl4 capable of hydrogen bonding? In H 2 O, only two of the six outer-shell electrons of oxygen are used for this purpose, leaving four electrons which are organized into two non-bonding pairs. The red N atom in each molecule is the point of attachment for a sugar molecule (ribose or deoxyribose). no. Subscribe to Blog via Email. What intermolecular forces does H2 have? A) CH4. Ungraded . Hence ethanol would have a lower boiling point than 1,2-ethanediol but ethane and dimethyl ether would both have lower boiling points. Does NH 3 have hydrogen bonding? Br2 has a higher boiling point than HF because of its large mass and size, which makes it more polarizable. Water, having hydrogen bound to an oxygen (which is much more electronegative than hydrogen, thus not sharing those bonded electrons very nicely) form dipoles of a special type called hydrogen bonds. Answer: Of the diatomic elements (H2, N2, O2, F2, Cl2, Br2, I2), all have dispersion forces. (A) dipole-dipole forces (B) London dispersion forces (C) hydrogen bonding (D) covalent bonding 16. H 2 = Molecular Hydrogen. Depending upon different contexts, its definition has been changing. Hydrogen bonding forces occurs in a particularly special group of polar compounds. Therefore, H2S has London dispersion forces and dipole – dipole intraction. Since in CHCL3 the hydrogen is not attached to fluorine, oxygen or nitrogen so people usually think that chloroform does not form hydrogen bonds. 2. Hydrogen bonding dominates all other intermolecular forces for small molecules. Q. These H-bonds are much stronger than the dispersion and dipole-dipole forces in the other compounds and hence these two compounds have the highest boiling points. dipole-dipole. forces are induced dipole forces. H 2 = Molecular Hydrogen. Tags: Question 8 . Hydrogen bonding occurs when hydrogen is bonded to a highly electronegative species (F, O, or N). Hydrochloric acid – does not contain Oxygen, Nitrogen or Fluorine, does not show hydrogen bonding. yes. Chemistry questions and answers. In total there are two pairs of non-bonding electrons in this compound and Hydrogen atoms have a complete valence shell. Hydrogen bonding refers to the formation of Hydrogen bonds, which are a special class of attractive intermolecular forces that arise due to the dipole-dipole interaction between a hydrogen atom that is bonded to a highly electronegative atom and another highly electronegative atom which lies in the vicinity of the hydrogen atom. As hydrogen bonding is usually the strongest of the intermolecular forces, one would expect the boiling points of these compounds to correlate with hydrogen bonding interactions present. Which one of the following molecules does NOT display hydrogen bonding? SURVEY . Its molecular orbitals are constructed from the valence-shell orbitals of each hydrogen atom, which are the 1s orbitals of the atoms. e) sulphuric acid, H 2SO 4, bonded as: van der Waals dispersion forces, dipole-dipole interactions and hydrogen bonding (It is an unsymmetrical molecule and so has a permanent dipole, and the hydrogens attached to Actually, water has all three types of intermolecular forces, with the strongest being hydrogen bonding. no. Hydrogen bond is a type of bond that occurs between a hydrogen atom and a more electronegative atom such as oxygen and nitrogen. The relatively large electronegativity difference between oxygen and hydrogen (about 2.3) is the reason why the partially positively charged (try to think why they are partially positively charged) hydrogens are attracted to the lone pairs on the oxygen atoms of other water molecules. The polar end of the soap molecules are attracted to each other. H 2 forms when two hydrogen atoms, H, are bonded together by a... See full answer below. Consequently it is the most common form of Hydrogen because it is stable with a neutral charge. The reason is hydrogen bonding.. Hydrogen bonding occurs when hydrogen is bonded to a highly electronegative species (F, O, or N). 12. Representation of the covalent … H2 forms when two hydrogen atoms, H, are bonded together by a. Consider the three compounds below, then choose the compound (s) that have hydrogen bonding. This is where electrons are shared between the atoms in order to fill there valence shells. This only means water has the most extensive hydrogen bonds as it forms two hydrogen bond per molecule. Adenine and guanine are purine bases found in both DNA and RNA. Doesn’t this mean that water has the strongest hydrogen bond? These compounds are characterized by the X-H bond, where X can be O, N, or F. Examples of compounds that exhibit hydrogen bonding forces are H 2 O, NH 3 and HF. All of the electron pairs—shared and unshared—repel each other. Which of the following substances will have hydrogen bonds between molecules? So, in order to the occurrence of hydrogen bond Fluorine must be attached with hydrogen. 5. Hydrogen bonds are strong intermolecular forces created when a hydrogen atom bonded to an electronegative atom approaches a nearby electronegative atom. According to earlier definitions “Hydrogen bonds is an interaction between the covalent pair A—H (donor) to a nearby electronegative atom B or X … Short answer: Hydrogen bond is formed between two molecules if they have hydrogen and any of the three electronegative atoms (N,O,F) covalently bonded to each other . In the chloroform molecule we can see that the central atom is the carbon, and one hydrogen and three chlorines are attached to it in a tetrahedral manner. Short answer: Hydrogen bond is formed between two molecules if they have hydrogen and any of the three electronegative atoms (N,O,F) covalently bonded to each other . Two superpositions of these two orbitals can be formed, one by summing the orbitals and the other … Which is the second strongest intermolecular force, after hydrogen bonding? Molecules made of more than one type of covalently bonded nonmetal atoms, like carbon dioxide gas (CO2), remain nonpolar if they are symmetrical or if their atoms have relatively equal pull. …. E. Identify the compound with the highest boiling point. H2SO4 has covalent bonds. Covalent bonds are formed by the sharing of electrons between the atoms. In sulphuric acid(H2SO4), there is a sharing of electrons between Sulphur and hydrogen(S-H) and Sulphur and Oxygen(S-O). They do not have a tendency to ionise or to make ionic bonds. hydrogen bonding is much stronger then dipole dipole intraction. Hydrogen atoms attached to very electronegative atoms like O and N have strong partial positive charge and are potential hydrogen bond donors. Why does hydrogen behave differently from other elements in its group when it comes to bonding? Does SO2 have hydrogen bonding? e) sulphuric acid, H 2SO 4, bonded as: van der Waals dispersion forces, dipole-dipole interactions and hydrogen bonding (It is an unsymmetrical molecule and so has a permanent dipole, and the hydrogens attached to to allow hydrogen bonding – and there is a hydrogen attached to it, so hydrogen bonding can happen.) The bonds are polar as the S is slightly positive and the O is slightly negative, so there is some intermolecular bonding happening there, but without hydrogen, they are not classified as hydrogen bonds. The figure on the left represents the function corresponding to +1s on the x,y,z coordinates while the figure on the right represents -1s function. Therefore, the answer is – option (d) – Hydrochloric acid. According to VSEPR … H2 is also called molecular hydrogen.It consists of two protons and two electrons. Hydrogen bonding c. London forces d. Covalent bond The correct answer is: Covalent bond Feedback Your answer is correct. HF. A hydrogen bond is the electrostatic attraction between polar groups that occurs when a hydrogen (H) atom bound to a highly electronegative atom such as nitrogen (N), oxygen (O) or fluorine (F) experiences attraction to some other nearby highly electronegative atom. Remember that hydrogen bonding requires a H bonded to an EN atom like F, O, or N. •••. the molecules are still very close to each other, therefore, very few of the hydrogen bonding forces will have to be overcome. 15. Hydrogen Bonding. to allow hydrogen bonding – and there is a hydrogen attached to it, so hydrogen bonding can happen.) As there is no (NOF) in H2S , there is no hydrogen bond there although it has dipole dipole forces. In the case of water, hydrogen bonding, which is a special case of polar dipole forces exerts a very strong effect to keep the molecules in a liquid state until a fairly high temperature is reached. Chemical structures of the five nitrogenous bases are shown below. OH, each have the least number of electrons but the highest boiling point of their respective series. What is a covalent bond? KCI-H2-H20-CH A) Which one of the following noble gases has the weakest London dispersion force? https://www.thoughtco.com/what-causes-hydrogen-bonding-603991 Chlorine and hydrogen are both non-metals. This is where electrons are shared between the atoms in order to fill there valence shells. H2O, more commonly known as water, is a covalent compound. This type of compound is the result of atoms, usually from nonmetal elements, sharing electrons. Water has a special type of covalent bond called a polar covalent bond. 3. Does H2 have strong intermolecular forces? general-chemistry. Think about where the lone pairs sit. Edit for reference in your reaction: H-H has a bond energy of ~430kJ/mol O=O 497 OH 463. so 2H2 + O2 --> 2H20. If the molecules have no dipole moment, (e.g., H2, noble gases etc.) Which is the second strongest intermolecular force, … There are two conditions for hydrogen bonding to occur: 1. The hydrogen in the molecule is bonded to a strongly electronegative atom (usually, N, O... Category: science chemistry. Representation of the covalent bond joining two hydrogen atoms in the H2 bond. I will give two answers ; one short and another a bit long Short answer: Hydrogen bond is formed between two molecules if they have hydrogen and an... CH4 actually can't form any hydrogen bonds. answer choices . The hydrogen bonds are many magnitudes stronger than other intermolecular forces in NH3; therefore, when examining intermolecular bonding in this molecule, other forces can be safely ignored. But the scenario is different. Answer: Hydrogen atoms in compounds such as H2 and H2O are joined to the molecule with covalent bonds. As there is no (NOF) in H2S , there is no hydrogen bond there although it has dipole dipole forces. 38 Votes) CH3OH and CH3CH2OH have hydrogen bonds due to the very electronegative O atom bonded to the H atom. Chlorine is in group 7 of the periodic table. Consider the three compounds below, then choose the compound (s) that have hydrogen bonding. Aug 13, 2016. Thymine and uracil are pyrimidine bases found in only DNA or RNA, respectively. Dihydrogen bond. hydrogen bonds have a distance of ~2.8 Å and some ultra-short hydrogen bonds have been reported with donor to acceptor distances of 2Å. The single-electron region is not as electron-rich as the N-O multiple bonds, so it does not have their repulsive power. Tags: Question 13 . This attraction created by hydrogen bonding keeps water in a liquid phase over a wide range of temperatures. c) CH3OH – Hydrogen bonding CH3SH – Dipole-dipole interaction Hydrogen bonding is the strongest intermolecular force, so CH3OH will have the higher boiling point. 4.8/5 (3,256 Views . Hydrogen can only form 1 bond. answer choices . Both H 2 O and H F have electronegative oxygen and fluorine atoms respectively in their molecule. What is the strongest type of intermolecular force present in H2. H,H,O-NH-HF Which one of the following has ion-dipole interaction? then the only interaction between them will be … A chlorine atom has 7 electrons in its outer shell. The hydrogen bond is responsible for many of the anomalous physical and chemical properties of compounds of N, O, and F. In particular, intermolecular hydrogen bonding is responsible for the high boiling point of water (100 °C) compared to the other group 16 hydrides that have much weaker hydrogen bonds. A hydrogen atom has 1 electron in its outer shell. chemical bonding - chemical bonding - Molecular orbitals of H2 and He2: The procedure can be introduced by considering the H2 molecule. When water goes from a liquid to a gas, the molecules must spread out; therefore, most of the hydrogen bonding forces will have to be overcome. Answer: Hydrogen atoms in compounds such as H2 and H2O are joined to the molecule with covalent bonds. Chemistry. But like you mentioned since Fluorine is more EN than Nitrogen, HF should have stronger IMFs and thus a higher boiling point. Hydrogen Bond is formed between Hydrogen atom and another atom, which is electronegative in nature. An atom will enter into H-bonding if it has the... Hydrogen bonding is a special type of dipole-dipole attraction between molecules, not a covalent bond to a hydrogen atom. Cytosine is a pyrimidine base found in both DNA and RNA. … The only reason a spark is even needed is because this reaction has a barrier in that you have to initially break the H2 bond in order to create the unstable state that will react readily. Water as a "perfect" example of hydrogen bonding Hydrogen bonding: This is a special kind of dipole-dipole interaction that occurs specifically between a hydrogen atom bonded to either an oxygen, nitrogen, or fluorine atom. All things have London dispersion forces...the weakest interactions being temporary dipoles that form by shifting of electrons within a molecule. Additionally, CCl4 is transparent in the hydrogen-bonded region; CCl4 thus constitutes an excellent, ambient … So, hold your seat end of out because we provide valuable information and also discuss about basic concept. H2 is not a free radical. Hydrogen iodide undergoes decomposition according to the equation 2HI (g) <==>H2 (g) + I2 (g) The equilibrium constant Kc at 425°C for this system is 0.018 . It tends to dissolve in water and the colorless aqueous solution is known as hydrofluoric acid. dispersion. The four electron pairs surrounding the oxygen tend to arrange themselves as far from … (CH3)3N. Remember Boron can only have three sigma bonds with no lone electrons. It consists of two protons and two electrons. The energy required to break the hydrogen bonds causes water to have a high heat of vaporization so that it takes a large amount of energy to convert liquid water into its gaseous phase, water vapor. Hydrogen bonds are especially strong dipole–dipole interactions between molecules that have hydrogen bonded to a highly electronegative atom, such as O, N, or F. What type of intermolecular attraction exists between H2 and H2? Qn: But then why does water have the highest boiling point among them? 2.) What you found on the internet wasn't entirely incorrect because they may have meant that water has 2 covalent bonds and can have 2 hydrogen bonds (4 bonds). H 2 is not a hydrogen bond but is a molecule in which hydrogen is bonded to itself. H2 is not a free radical. RULE 3: Bonding angles matter, the more ideal the bonding angle, the stronger the hydrogen bond. A water molecule consists of two hydrogen atoms bonded to an oxygen atom, and its overall structure is bent. Hydrogen fluoride is a colorless liquid or a gaseous compound having the chemical formula HF. (C) hydrogen bonding (D) covalent bonding 15. $\begingroup$ Water can form 2 hydrogen bonds, as oxygen has a 2δ− partial charge, therefore it attracts to hydrogen atoms with a δ+ bond to it. If you liken the covalent bond between the oxygen and hydrogen to a stable marriage, the hydrogen bond has "just good friends" status. Hydrogen bonds vary in strength. Because nonpolar molecules share their charges evenly, they do not react to electrostatic charges like water does. The nonpolar ends of the soap molecules stick out from the water and help hold bubbles together. Hydrogen bonds have about a tenth of the strength of an average covalent bond, and are being constantly broken and reformed in liquid water. Hydrogen bonding is a special type of dipole-dipole interaction that occurs between the lone pair of a highly electronegative atom (typically N, O, or F) and the hydrogen atom in a N–H, O–H, or F–H bond. When the electron cloud of a molecule is easily distorted, the molecule has a high _____. Hydrogen bonding is a specific term for a particularly strong dipole-dipole interaction between a hydrogen atom and a very electronegative atom (oxygen, fluorine, or nitrogen). C) Water has an exceptionally high specific heat capacity. - Iodine is in Group VIlA, so it has an oxidation number of -1 in both the reactant 12 and product HI. 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